Aqua[N-phenyl-2-(quinolin-8-yloxy)acetamide]dinitratozinc(II)
نویسندگان
چکیده
In the title complex, [Zn(NO(3))(2)(C(17)H(14)N(2)O(2))(H(2)O)], the six-coordinated Zn atom is in a distorted octa-hedral geometry, the donor centers being two O atoms and one N atom from the tridentate organic ligand, a water O atom and two O atoms from two monodentate nitrate ions. In the crystal, O-H⋯O hydrogen bonds between the coordinated water mol-ecules and nitrate O atoms and N-H⋯O hydrogen bonds between the main ligand and nitrate O atoms consolidate the three-dimensional network.
منابع مشابه
N-Methyl-N-phenyl-2-(quinolin-8-yloxy)acetamide monohydrate
In the title compound, C(18)H(16)N(2)O(2)·H(2)O, the dihedral angle between the quinoline ring system and the benzene ring is 87.19 (8)°. In the crystal, water mol-ecules are linked to acetamide mol-ecules via inter-molecular O-H⋯N and O-H⋯O hydrogen bonds.
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In the title compound, 2C(18)H(16)N(2)O(2)·H(2)O, the dihedral angles between the quinoline rings and the benzene rings in the two independent acetamide mol-ecules are 80.09 (5) and 61.23 (5)°. The crystal packing is stablized by O-H⋯N and N-H⋯O hydrogen bonds between the acetamide and water mol-ecules.
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In the title complex, [CuCl(2)(C(18)H(16)N(2)O(2))(2)]·CH(3)CN·H(2)O, the six-coordinated Cu atom is in a distorted octa-hedral geometry with the donor centers of two O atoms and two N atom from two bidentate ligands, and two chloride ions. In the crystal, pairs of inter-molecular N-H⋯ Cl hydrogen bonds form centrosymmetric dimers and inter-molecular O-H⋯ O hydrogen bonds between the ligand and...
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In the title mononuclear complex, [HgI(2)(C(12)H(11)NO(3))], the Hg(II) ion has a distorted trigonal-planar coordination sphere defined by two I(-) anions and the N atom of a methyl 2-(quinolin-8-yl-oxy)acetate ligand. In the crystal, face-to-face π-π stacking inter-actions, with a centroid-centroid distance of 3.563 (9) Å, are observed.
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In the title compound, [Ir(C(11)H(8)N)(2)(C(12)H(10)NO)(H(2)O)]·0.5C(2)H(6)O(2), the iridium center is coordinated by two N atoms and two C atoms from two 2-(2-pyrid-yl)phenyl (ppy) ligands, one N atom from the N-(1-naphth-yl)acetamide ligand and one water O atom, forming a distorted octa-hedral environment. Mol-ecules are linked by inter-molecular O-H⋯O hydrogen bonds formed by the coordinated...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010